Snell's law
n₁ sin θ₁ = n₂ sin θ₂. The ratio of the sines of the incidence and refraction angles at an interface equals the inverse ratio of refractive indices. Derived by Snell 1621 (unpublished), Descartes 1637 (published).
Definition
Snell's law states that at an interface between two transparent media of refractive indices n₁ and n₂, an incident ray making angle θ₁ with the surface normal refracts into a transmitted ray at angle θ₂ satisfying n₁ sin θ₁ = n₂ sin θ₂. The transmitted ray bends toward the normal when entering a denser medium (n₂ > n₁, so θ₂ < θ₁) and away from the normal when entering a less dense medium. Above the critical angle θ_c = arcsin(n₂/n₁) when going from denser to less dense, no transmitted ray exists and total internal reflection takes over.
The law can be derived three ways: from Fermat's principle of least time applied to a path crossing the interface; from matching the tangential component of the wavevector k across the boundary (k_∥ must be continuous, giving n₁ sin θ₁ = n₂ sin θ₂ for light of fixed frequency); or from Huygens's secondary-wavelet construction at the boundary. Snell derived it experimentally in 1621 by meticulous angle-measurement across glass, water, and other media; he never published. Descartes independently derived and published in 1637, and French texts called it "Descartes's law" for two centuries; Huygens rediscovered Snell's original derivation in the 1670s and the Snell name prevailed in English and Dutch usage. Every geometrical-optics analysis — lens design, fibre-optic coupling, underwater optics — starts from Snell's law.