Anomalous magnetic moment
The deviation of the electron's gyromagnetic ratio from the Dirac value g = 2: a_e ≡ (g − 2)/2 = α/(2π) + O(α²) ≈ 0.00115965218... — the most precisely-tested prediction in physics, agreeing with experiment to 12 decimal places. Schwinger's 1948 calculation was the first triumph of QED.
Definition
The anomalous magnetic moment of the electron is the small but measurable deviation of the electron's gyromagnetic ratio g from the Dirac value g = 2 predicted by relativistic quantum mechanics with a structureless point electron. The defining quantity is a_e ≡ (g − 2) / 2, the fractional anomalous excess. The Dirac equation alone predicts a_e = 0; QED's one-loop vacuum-polarisation and vertex corrections give Schwinger's 1948 leading-order result a_e = α / (2π) ≈ 0.00115965, the first triumph of perturbative quantum electrodynamics and one of the most-quoted single-line formulas in twentieth-century physics.
Higher-order corrections have been computed to five-loop accuracy: a_e = (α/2π) − 0.328 (α/π)² + 1.182 (α/π)³ − ... The five-loop value of a_e is known theoretically to about 12 significant figures and agrees with the experimental measurement (Penning-trap measurements of trapped electrons, Hanneke-Fogwell-Gabrielse 2008 and refinements through 2023) to about the same precision. The electron magnetic moment is therefore the most-precisely-tested prediction in all of physics. The muon's anomalous magnetic moment a_μ shows a small but persistent ~4σ tension between the Standard Model prediction and the Brookhaven E821 (2001) and Fermilab Run-1 + Run-2 (2021–2023) measurements, of intense interest as a possible signal of physics beyond the Standard Model — though improvements in the QCD hadronic-vacuum-polarisation calculations have somewhat reduced the tension. The clean agreement for the electron and the persistent puzzle for the muon are emblematic of how precisely classical electromagnetism, in its quantum-electrodynamic completion, has been pinned down by experiment.